Synthesis of N-benzoyl-N-Benzylidenemeso-1-2-diphenylethylenediamine (Adduct), a nucleophilic addition reaction to the carbonyl group of benzaldehyde and microwave-assisted dimerization
DOI:
https://doi.org/10.54495/Rev.Cientifica.v12i1.349Keywords:
synthesis, n-benzoyl-n-benzylidenemeso-1-2-diphenylethylenediamine, reaction, nucleophilic addition, carbonyl group, benzaldehyde, microwave-assisted dimerizationAbstract
This work is based on reacting an amine to a carbonyl aldehyde substrate (ammonium acetate to benzaldehyde) using microwave energy and also in the absence of solvents to obtain “mineral and di-iminic” compounds*1 (N- benzoyl-N-benzylidenemeso-1:2-diphenyl-ethylenediamine) that are currently used in the selective epoxidation of olefinic polymers (1). The classic procedure for obtaining these compounds involves excessive heating and reflux (2) so irradiation of the reaction mixture with microwave energy (M.O.) represents a less cumbersome and faster way of obtaining.
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W. Zhang, J. L, Loebach. S. R. Wilson and E. N. Jacobsen, J. Am. Chem. Soc. 112, (1990), https://doi.org/10.1021/ja00163a052 DOI: https://doi.org/10.1021/ja00163a052
S. Trlppeff, J. Chem. Soc., (1957), 4407-4408.
H. M. Kingston, L. B Jassie, Introduction to Microwave Sample Preparation Theory and Practice. American Chemical Society, Washington D, C, E.E.U.U. 1988.
Alumina-Mediated Microwave Thermolysis: A New Approach to Deprotection of Benzyl Esters. R.S. Varma y colaboradores: Tet rahedron Lett. 34, 4603 (1993), https://doi.org/10.1016/S0040-4039(00)60635-4 DOI: https://doi.org/10.1016/S0040-4039(00)60635-4
Selective Oxidation of Sulfides to Sulfoxides or Sulfones on Sodium Periodate uDopedu Silica Surface and Microwave irradiation. R. 5. Varma y colaboradores Tetrahedron Lett. 38, 6525 (1997), https://doi.org/10.1016/S0040-4039(97)01520-7 DOI: https://doi.org/10.1016/S0040-4039(97)01520-7
Synthesis of Substituted Diphenylamines. Mark Baush. de: Chemistry and Biochemistry Southern Illinois University at Carbondale (1997).
Microwave Thermolysis with Clayfen: Soivent Free Oxidation of Sulfides to Sulfoxides. FL 8. Varma and R. Dahiya: Synth. Commun., 1998-en prensa.
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Copyright (c) 1999 Franz Barrios, Pedro Ordoñez, Edgar Goḿez
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