Quantification of Methyl Terbutyl Ether (MTBE) in gasoline, distributed in Guatemala City, by gas chromatography

Authors

  • Edwin Taracena University of San Carlos of Guatemala
  • José Roberto Benavides University of San Carlos of Guatemala

DOI:

https://doi.org/10.54495/Rev.Cientifica.v12i1.350

Keywords:

quantification, methyl terbutyl ether (MTBE), gasoline, Guatemala City, gas chromatography

Abstract

In the present work, an attempt was made to determine the presence and percentage of antiknock, specifically Methyl-tert-butyl-ether (MTBE), contained in gasoline used in Guatemala City. MTBE, crude Naphtha and gasoline of different brands were analyzed by means of gas chromatography, specifically using the Perkin Elmer model 8,500 chromatograph and a Supelco Wax 10 capillary “Wide Bore” column, 0.55 mm OD x 30 m long. (from Poli-etHen glycol), to determine if the gasoline used in the City contains MTBE and in what percentage. For this purpose, CRUDE NAFTA and MTBE are injected, to establish under what conditions a better separation of the antiknock peak was achieved. in the chromatogram Once the best separation conditions have been established, mixtures of known concentration of MTBE are injected into NAFTA in order to prepare a calibration curve and with this, establish the MTBE content in the different brands of gasoline, estimating that it stops. “regular” type gasolines are between 11 and 16% vlv, and for “super” type gasolines between 6 and 9% vlv.

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References

Archive-name Autosigasolíne-faq/part I Posting-Frequency: Monthly Last-modified 30 May 1996

Anal. Chem. 64 :3202-5 D 15 '92, Determination of ethers and alcohols in Gasolines by G.C./fourier transform infared spectroscopy, https://doi.org/10.1021/ac00048a021 DOI: https://doi.org/10.1021/ac00048a021

Chemtech 18 : 1 20-2 F ’88. Getting the lead out with ethil t-butyl ether

ASTM 1997. ASTM O 46L5-94a Standard test method for determination of MTB E, ETBE, TAME, DIPE, tertiary-amyl alco- hol an C1 a C4 alcohols in gasoline by gas chomatography.

http://chem.external.hp.com/scnptslcag_Lit PDF. asp?¡WHID=7168&SortBy=10

Published

1999-12-31

How to Cite

Taracena, E., & Benavides, J. R. (1999). Quantification of Methyl Terbutyl Ether (MTBE) in gasoline, distributed in Guatemala City, by gas chromatography. Revista Científica, 12(1), 48–50. https://doi.org/10.54495/Rev.Cientifica.v12i1.350

Issue

Section

Original Research Papers

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