Estudio preliminar de la obtención de compuestos híbridos  de quitosano y polifenoles derivados de lignina a partir de  subproductos agropecuarios y pesquería de camarón

Mary Lopretti Correa; Marianelly Esquivel Alfaro; Sergio Madrigal Carballo; Yendry Corrales Ureña; José Vega-Baudrit

doi:10.54495/Rev.Cientifica.v27i1.74

Authors

Mary Lopretti Correa Facultad de Ciencias, Universidad de la República y Bioprocesos LATU
Marianelly Esquivel Alfaro Laboratorio de Polímeros, Escuela de Química, Universidad Nacional
Sergio Madrigal Carballo Laboratorio de Polímeros, Escuela de Química, Universidad Nacional
Yendry Corrales Ureña Laboratorio Nacional de Nanotecnología LANOTEC-CeNAT-CONARE
José Vega-Baudrit Laboratorio Nacional de Nanotecnología LANOTEC-CeNAT-CONARE

DOI:

https://doi.org/10.54495/Rev.Cientifica.v27i1.74

Keywords:

conjugates, lignin, chitosan, protein, microcapsules

Abstract

Hybrid microcapsules of the conjugate of polyphenols derived from lignin were prepared and characterized. They were obtained from pineapple peel and chitin from shrimp shell from agroindustry or shrimp fishery of Costa Rica. The phenolic compounds were obtained by hydrolysis of lignin, using the enzyme derivatives from the fungus culture of Gloeophyllum trabeum (Pers.) Murrill and Phanerochaete chrysosporium Burdsall. The reaction was carried out in a reactor with atmospheric pressure, pH 6.8, with a citrate buffer of 1M, for 6 hours at 37°C. The chitosan was obtained by alkaline deacetylation of the Heterocarpus vicarious Fazon, shrimp exoskeletons. Microcapsules were prepared mixing a solution of chitosan dissolved in acetic acid and a solution of polyphenol derivatives from lignin. Afterwards, they were added to a vaseline aqueous solution for the microemulsion formation and glutaraldehyde was added as a crosslinking agent. Microcapsules with sizes between 5 to 10 µm were obtained. These microcapsules are a promising material to increase chitosan solubility and for preventing the oxidation of polyphenols. The preliminary results obtained in this research show the potential of this material for the encapsulation of drugs and pesticides.

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